Organometallic Reactions Part 3: Reductive Elimination
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Organometallic Reactions Part 3: Reductive Elimination
With oxidative addition understood, let's check the precise reverse process, reductive elimination. This is way for two ligands to be removed from a transiti...
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Reductive Elimination Mechanism
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The Buchwald–Hartwig amination forms aryl–amine bonds by coupling aryl halides with amines under palladium catalysis. The reaction proceeds through a Pd(0)/Pd(II) cycle involving oxidative addition, amine coordination and deprotonation, and reductive elimination. Early studies by Buchwald and Hartwig established the basic catalytic framework, and subsequent work from many groups broadened the reaction’s scope and reliability. Today it is one of the most versatile C–N bond-forming methods in synt
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